Fluid treatment apparatus

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Drawing sheet — no readable text.

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to a reaction zone adjacent the bottom of the pipe and

FLUID TREATMENT APPARATUS recirculated upwardly through a second pipe, which surrounds the inner pipe, following the reaction. Com

This application is a divisional application of my U.S. pressed air is injected into the downwardly flowing Application Ser. No. 755,880, filed July 17, 1985, now 5 sludge preferably in the form of Taylor-type gas bub U.S. Pat. No. 4,671,351. bles. In the McGrew patent, the temperature of the reaction is controlled by a heat exchanger jacket which

BACKGROUND OF THE INVENTION surrounds the inner concentric pipes wherein heated oil 1. Field of the Invention or other heat exchange fluid is pumped into the jacket This invention relates to an improved insulated tubu 10 to control the temperature of the reaction zone. lar and heat exchanger and a continuous fluid treatment The fluid treatment apparatus of this invention pref. apparatus such as may be used in down-hole wet oxida erably utilizes a centrally located heat exchanger tion of fluid waste streams, including municipal sludge. wherein the fluid to be treated is contained within recir 2. Description of the Prior Art culating pipes which surround the heat exchanger, re Above ground wet oxidation systems have been in 15 sulting in better control of the temperature of the reac use for several years with limited success for the treat tion zone and more efficient heating of the fluid to be ment of municipal sludge received from a sewage treat treated. The center downcomer pipe of the heat ex ment process. The above-ground wet oxidation systems changer is preferably an insulated tubular which com use high surface pressure and heat to initiate the wet prises two concentric pipes or tubes telescopically oxidation reaction, however, the apparatus is not en 20 nested in spaced relation wherein the space between the ergy efficient, the system is subject to failure and results tubes is sealed and preferably filled with an inert gas. As in only partial oxidation of the sludge; see for example, will be understood, the pipes and insulated tubular used U.S. Pat. No. 2,665,249 of Zimmermann and U.S. Pat. in the fluid treatment apparatus of this invention com No. 2,932,613 of Huesler, et al. The above ground wet prises a series of pipes interconnected in a vertical string oxidation processes have not therefore replaced the 25 to accommodate the length of the overall fluid treat traditional methods of treating municipal sludge, which ment apparatus. Insulated tubulars have been used in the includes settling, dewatering, drying, incineration and oil well industry and other industries for several years the like. to transfer heated fluids and gases. As set forth herein Various vertical or down-hole fluid treatment sys below, however, the fluid treatment apparatus of this tems have been proposed by the prior art but are used 30 invention requires localizing the heat as much as possi only in very limited applications. A down hole fluid ble in the reaction zone located adjacent the bottom of treatment system utilizes vertical pipes which generally the pipes. The heated oil or other heat transfer fluid is extend downwardly into the ground from a control received at the top of the apparatus or ground level. station. The fluid to be treated is pumped into the verti Thus, radial heat losses through the insulated tubular to cal reactor pipes and the fluid head creates a pressure 35 the recirculated heat transfer fluid must be minimized. which assists in the desired fluid process or reaction. In It has now been found that a substantial heat loss results the processes used to date, the reaction requires addi from atomic hydrogen permeation into the space be tional heat which may be added by electrical resistance tween the tubes of the insulated tubular which recom coils or heated fluid which circulates in a heat ex bines to form gaseous hydrogen. There is therefore a changer. Air or other gases may be added to the fluid 40 need to develop an improved insulated tubular which being treated to assist in the reaction. inhibits hydrogen permeation to improve the insulation Although several prior art patents propose a vertical qualities of the insulated tubular which results in an well wet oxidation reaction system for treatment of improved heat exchanger and fluid treatment apparatus municipal sludge or other fluid waste streams, the pro of the type disclosed herein.

cesses and apparatus disclosed in these patents have not 45 SUMMARY OF THE INVENTION been successful; see for example U.S. Pat. No.

3,449,247. As recognized by these prior art patents, the As described, the heat exchanger and insulated tubu pressure created by the fluid head is dependent upon the lar of this invention is particularly, although not exclu length of the reactor. Thus, it is theoretically possible to sively, adapted to utilization in a fluid treatment appara fully oxidize municipal sludge at a depth of approxi 50 tus for continuous treatment of fluid waste at elevated mately one mile provided the concentration of the oxi temperatures and pressures, such as down-hole fluid dizable material in the municipal sludge is balanced treatment apparatus including wet oxidation of munici against the oxygen available in the air injected into the pal sludge and other fluid wastes. The preferred heat system. To the applicant's knowledge, however, no one exchanger includes an elongated insulated tubular pref has been successful in building a down-hole wet oxida 55 erably having an open end which is generally concen tion system for municipal sludge except the assignee of tric with and telescopically nested in a second pipe the present invention. preferably having a closed end adjacent the open end of U.S. Pat. No. 4,272,383 of Dr. McGrew, entitled the surrounding pipe to communicate with the insulated "Method and Apparatus for Effecting Subsurface, Con tubular. The insulated tubular includes a first inner tube trolled, Accelerated Chemical Reactions', assigned to 60 and a second outer tube which is preferably generally the assignee of the present invention, discloses the prin concentric with and surrounds the first tube in spaced ciples of the first successful down-hole wet oxidation relation. The space between the first and second tubes is reaction system for municipal sludge which is now preferably sealed and filled with an inert gas, such as operating on an experimental basis in Longmont, Colo. argon, helium or xenon. The heat transfer fluid such as The apparatus disclosed in the McGrew patent includes 65 oil is received in the first inner tube of the insulated a series of generally concentric telescopically nested tubular preferably at an elevated temperature. The heat pipes or tubes wherein diluted municipal sludge is pref. transfer fluid then flows through the insulated tubular erably received in the inner pipe and flows downwardly and returns through the annular space between the

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outer tube of the insulated tubular and the downcomer "coating' of an iron-aluminum alloy. The iron pipe containing fluid and oxidizing gas for heating and aluminum alloy coating has been found to be particu recirculation. larly effective in preventing diffusion of atomic hydro In the most preferred embodiment of the heat ex gen into the sealed space between the tubes. The diffu changer, the insulated tubular includes a hydrogen per sion barrier may also be formed by electroplating cop meation barrier on the inner and outer surfaces of both per or preferably nickel on the surfaces of the tubes. As tubes of the insulated tubular. The hydrogen perme described, the diffusion of atomic hydrogen into the ation barrier is preferably formed by coating the inner sealed space between the tubes of the insulated tubular and outer surfaces of the tubes with aluminum, nickel or results in an increased thermal conductivity and resul copper. The permeation barrier reduces the flow of 10 tant increased radial heat losses from the heat transfer atomic hydrogen into the space between the first and fluid flowing through the insulated tubular to the recir second tubes of the insulated tubular, thereby reducing culating heat transfer fluid in the second outer pipe of heat losses from the hot transfer fluid in the center tube the heat exchanger.

of the insulated tubular to the returning heat transfer The method of forming an insulated tubular for use in fluid in the annular region whose inner surface is the 15 a heat exchanger apparatus, as described, thus includes outer surface of the insulated tubular. When the heat forming the telescopically nestable tubes, forming a exchanger of this invention is submerged in a fluid, the hydrogen permeation barrier coating on the exterior heat transfer is concentrated in a reaction zone located and interior surfaces of the tubes and assembling the adjacent the end of the heat exchanger, which is partic tubes in nested, concentric, telescopically spaced rela ularly advantageous in the down-hole fluid treatment 20 tion and sealing the space between the tubes. The space apparatus of this invention. The elongated fluid heat between the tubes is then evacuated and preferably exchanger is then surrounded by circulation pipes con filled with an inert gas. In the most preferred method of taining the fluid to be treated. The circulation pipes forming the insulated tubular of this invention, the hy include a first pipe which telescopically surrounds the drogen permeation barrier coating is formed by diffu outer pipe of the heat exchanger in spaced relation 25 sion coating the interior and exterior surfaces of the which receives the fluid to be treated in contact with tubes with aluminum, forming an iron-aluminum alloy the outer pipe of the heat exchanger. A second pipe on the surfaces. As described, the hydrogen permeation generally concentric with and surrounding the first pipe barrier may also be formed by electroplating the sur receives the treated fluid. The fluid to be treated, such faces with nickel or the barrier may also be formed by as municipal sludge or other fluid waste is received 30 electroplating copper on the surfaces. between the outer pipe of the heat exchanger and the Other advantages and meritorious features of this first pipe of the fluid circulation pipes. The fluid to be invention will be more fully understood from the foll treated flows through the first pipe in contact with the lowing description of the preferred embodiments, the heat exchanger and recirculates through the second appended claims, and the drawings, a brief description outermost pipe. In this embodiment, the fluid treatment 35 of which follows.

apparatus thus creates a fluid reaction zone adjacent the BRIEF DESCRIPTION OF THE DRAWINGS end of the fluid circulation pipes.

As described, the fluid treatment apparatus of this FIG. 1 is a schematic illustration of a preferred em invention is particularly suitable for continuous treat bodiment of the continuous fluid treatment apparatus of ment of fluid waste including municipal sludge and this invention; and contaminated fluid waste at elevated temperatures and FIG. 2 is a cross-sectional view of the lower portion pressures. Where the fluid treatment apparatus is uti of the fluid treatment apparatus shown in FIG. 1. lized to treat municipal sludge and other waste by wet DESCRIPTION OF THE PREFERRED oxidation, the fluid treatment apparatus comprises a EMBODIMENTS AND METHOD OF THIS plurality of elongated generally concentric and tele 45 INVENTION scopically nested pipes which extend vertically into the ground as much as a mile or more in depth. The central The continuous fluid treatment apparatus 20 illus insulated tubular, which receives the hot heat transfer trated in the drawings is a vertical down hole fluid fluid, preferably has an open end and the outer pipe of reaction apparatus suitable for treatment of various the heat exchanger preferably has a closed end adjacent 50 contaminated fluid wastes including wet oxidation the open end of the insulated tubular providing commu treatment of municipal sludge. As disclosed in the nication with the insulated tubular and continuous flow above-referenced McGrew patent, the fluid treatment of the heat transfer fluid. The first pipe of the fluid apparatus comprises a plurality of generally concentric circulation pipes, which surrounds the outer pipe of the and telescopically nested pipes which extend vertically heat exchanger, also has an open end and the outermost 55 into the ground. In a treatment apparatus for wet oxida pipe may also have a closed end which communicates tion of municipal sludge, for example, the pipes may with the open end of the fluid circulation pipes, provid extend approximately one mile into the ground creating ing continuous circulation of the fluid to be treated. The a very substantial pressure head. It will be understood, heated reaction zone is thus located adjacent the bottom however, that the length of the pipes will depend upon of the fluid circulation pipes and the pressure of the 60 the fluid being treated and the desired fluid reaction. fluid head in the circulation pipes assures fluid reaction The fluid treatment apparatus of this invention may also of the fluid waste at elevated temperatures and pres be used in various conversion reactions wherein a solid sures in the reaction zone. particulate is suspended in the circulating fluid. Further, In the most preferred embodiment of the heat ex the pipes or tubes are generally not continuous. Each changer and fluid treatment apparatus of this invention, 65 pipe comprises a plurality of sections which are inter the hydrogen diffusion barrier is a diffusion coating of connected in serial alignment in a string, similar to the aluminum on the inner and outer surfaces of the concen pipes in an oil well. In a typical municipal sludge wet tric tubes of the insulated tubular, forming a surface oxidation application, the length of each pipe section is

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40 feet long, the total length is about 5,200 feet and the top of pipe 28 through line 74, back to reservoir 40 flow rate of the fluid being treated is about 80 to 400 through valve 76.

gallons per minute. The fluid to be treated, such as contaminated indus In the disclosed preferred embodiment of the fluid trial fluids, municipal sewage or the like is supplied to treatment apparatus of this invention, the fluid heat the top of pipe 32 and circulates around the heat ex exchanger 22 is located at the center of the concentric changer 22 as described. As shown in FIG. 1, the fluid pipes of the fluid treatment apparatus. The first or inner to be treated is stored in reservoir tank 80. As described most pipe of the heat exchanger is an insulated tubular in the above referenced McGrew patent, the fluid treat 24 having an open end 26. As described more fully ment apparatus is particularly suitable for treatment of hereinbelow, the insulated tubular reduces radial heat 10 municipal sludge received from a conventional munici transfer from the downflowing heated heat transfer pal wastewater treatment plant. The sludge is received fluid in the insulated tubular to the recirculating up through line 82 and the flow is controlled by line 84. wardly flowing heat transfer fluid in the second pipe 28. The fluid sludge is then delivered to the apparatus As shown, the first pipe or insulated tubular 24 is gener through line 86 and valve 88. The fluid sludge is prefer ally concentric with and telescopically nested in second 15 ably diluted with liquid effluent from municipal waste pipe 28 and the second pipe has a closed end 30 adjacent water treatment plant delivered through line 90 and the open end 26 of the insulated tubular. The fluid to be valve 92. The fluid sludge is preferably diluted to con treated is then circulated around the heat exchanger 22, trol the percentage of oxidizable material delivered to as now described. the fluid treatment apparatus. The diluted fluid sludge, A third pipe 32, which is the first pipe of the outer 20 fluid waste or other fluid to be treated then flows down fluid circulation piping, surrounds the heat exchanger wardly through pipe 32 in contact with the outer wall 22 in generally concentric spaced telescopic relation. 28 of the heat exchanger 22 as shown by arrows 94. As The third pipe 32 has an open end 34 adjacent the closed described, pipe 32 has an open end 34 and the treated end 30 of the fluid heat exchanger. A fourth pipe 36 fluid then flows upwardly through the outer pipe 36 for surrounds the third pipe 32 in generally concentric 25 discharge from the fluid treatment apparatus. As shown spaced telescopic relation and includes a closed end 38 in FIG. 1, the treated fluid is discharged from pipe 36 adjacent the open end 34 of the third pipe 32. The fluid through line 98 to tank 100. Where the apparatus is used to be treated is circulated downwardly through pipe 32 for wet oxidation of fluid sludge, tank 100 is preferably in contact with the second pipe 28 of the heat exchanger a settling tank where the substantially inert ash is sepa 22 and the treated fluid then flows through the open end 30 rated from the water. The ash may be drawn off 34 of the third pipe 32 and upwardly through the fourth through line 102 and the rate of flow is controlled by pipe 38 in contact with the outer surface of the third valve 104.

pipe 32. As described in the above-referenced McGrew In a wet oxidation reactor, the supernatant may be patent, the fluid treatment apparatus creates a reaction drawn off through line 106 and used as a diluent in the zone adjacent the bottom of the apparatus wherein the 35 process. As shown in FIG. 1, the supernatant is drawn fluid to be treated is reacted under heat and pressure. A off through line 106 and delivered to line 86 which principal object of the present invention is to concen communicates with pipe 32. The rate of flow and dilu trate the heat transferred from the heat exchanger to the tion is controlled by valve 108. As described in the fluid circulating in pipe 32 to the lower reaction zone, above-referenced McGrew patent, air is injected into and reduce radial heat transfer, particularly in the upper the down-flowing sludge in wet oxidation of municipal portion of the heat transfer apparatus. sludge and other waste materials. The air is preferably FIG. 1 illustrates schematically the above-ground injected into the down-flowing stream of the fluid to be components utilized in the fluid treatment apparatus treated below the ground level 39 in the form of Taylor and process. The heat transfer fluid, such as oil, is stored type bubbles. It will also be understood that other fluid in a reservoir tank 40. The oil is heated in a heater 42, 45 reactions may require other gases dependent upon the such as a conventional gas fired heater. The oil is desired reaction. The disclosed apparatus therefore pumped by pump 44 from reservoir 40 through line 46 includes an air compressor 110 and the compressed air is to heater 42 and the rate of flow is controlled by valve delivered to the downward flowing fluid to be treated 52. The heated oil is then transferred through line 48 in pipe 32 below ground level by line 112 and the flow and the rate of flow is controlled by valve 50. Where 50 is controlled by valve 114. 110 may also be a pump the fluid reaction is exothermic, such as a wet oxidation delivering any gas required by the reaction occurring in reaction, cooling of the reaction zone may be required the fluid treatment apparatus of this invention. where the heat of reaction exceeds the preferred tem As described, the fluid treatment apparatus of this perature in the reaction zone. Thus, the disclosed appa invention is primarily intended to treat fluid waste at ratus includes a heat exchanger 54 where the oil may be 55 elevated temperatures and pressures. The pressure is cooled. The oil from reservoir 40 may be pumped provided by the fluid head and the temperature is pro through line 56 to the heat exchanger 54 by pump 57. vided by the heat of reaction where the reaction is The flow is controlled by line 62. The cooler oil is then exothermic and the heat exchanger 22. In a typical wet discharged through line 58 and valve 60 to the supply oxidation reaction of municipal sludge, the bottom hole line 48 of the fluid treatment apparatus. 60 temperature is approximately 500 degrees Fahrenheit. Normally heated oil is then supplied through line 48 Thus, the oil delivered to the second or outer pipe 28 of into the top of the insulated tubular 24. As best shown in the heat exchanger should be in excess of 500 degrees FIG. 2, the heated oil then flows downwardly through Fahrenheit. In a typical wet oxidation reaction, the oil the insulated tubular as shown by arrow 70. The oil then will be delivered to the inlet of the insulated tubular 24 flows out of the open end 26 of the insulated tubular and 65 at a temperature of about 700 degrees Fahrenheit. The the oil is recirculated upwardly through pipe 28 in oil or other heat transfer fluid then flows downwardly contact with the tubular, as shown by arrow 72. The oil to the open end 26 of the insulated tubular, where it is or other heat transfer fluid is then discharged from the delivered to the outer pipe 28 of the heat exchanger at

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a temperature of about 525 to 550 degrees Fahrenheit. diffusion coatings are commonly applied to steel fur The fluid then flows upwardly through pipe 28 as nace tubes and the like to improve corrosion resistance shown by arrow 72 of FIG. 2 and heats the down-flow and furnace life by a process known as "Alonizing'. In ing fluid to be treated which contacts the outer surface the Alonizing process, the pipe is packed externally and of pipe 28 in pipe 32. The temperature of the oil at the internally with aluminum and alumina powder - and top exit of the pipe 28 is about 150 degrees Fahrenheit. placed in a furnace at about 1700 degrees Fahrenheit for As described, the fluid reaction occurs in a reaction three to four days. The coating is very hard and does zone where temperature of the down-flowing fluid not interfere with welding. It has now been discovered exceeds 350 degrees Fahrenheit. The preferred embodi that an Alonized aluminum-iron diffusion coating sub ment of the fluid treatment apparatus therefore utilizes 10 stantially reduces atomic hydrogen diffusion. an insulated tubular 24 to reduce the radial heat transfer

The hydrogen from the down-flowing heat transfer fluid in the insu formed by electroplating diffusion barrier coating may also be lated tubular 24 to the cooler heat transfer fluid in line nickel on the interior and 28. The details of the insulated tubular 24 are disclosed exterior surfaces of the tubes. The electroplated nickel in FIG. 2. The insulated tubular includes an inner tube 15 coating also provides an excellent atomic hydrogen 120 having outer and inner surfaces 122 and 124, respec diffusion barrier, not quite as good as the Alonized tively, and an outer tube 126 having outer and inner surfaces. Finally, the hydrogen diffusion barrier may be surfaces 128 and 130, respectively. The inner tube 120 is formed by electroplating copper on the surfaces of the preferably concentric with and telescopically nested tubes, however, copper will interfere with welding and within the outer tube 126 in spaced relation. The space 20 may adversely affect the strength properties of the 132 between the tubes is fixed and sealed with a sealing tubes. Where the surface is electroplated with nickel or ring 134 which may be welded or otherwise secured in copper, the thickness of the coating should be approxi the space between the tubes. The space between the mately 0.001 mm. Comparing bare steel with a hydro tubes is then evacuated and filled with an inert gas such gen permeation barrier coated insulated tubular, the as argon, helium and xenon. The inert gas has a low 25 coated insulated tubular had a hydrogen permeation thermal conductivity, reducing the radial heat transfer rate reduced by a factor of about 1000. Comparing through the space 132 between the tubes 120 and 126. Alonized steel with a nickel plated steel, the permeation The heat transfer across the space 132 between the rate was reduced by a factor of about 10. Thus, the most tubes is defined by the following equation: preferred embodiments includes a hydrogen diffusion 30 barrier formed by diffusion coating of aluminum, form ing an iron-aluminum alloy. The hydrogen diffusion barrier wherein Q is the heat transferred in btu per hour, k is ing qualities substantially reduces degradation of the insulat the thermal conductivity, A is the area for heat transfer, of the insulated tubular. The method of forming an insulated tubular thus

At/Ar is the radical temperature gradient. In the wet 35 includes oxidation apparatus operating experimentally at Long forming telescopically nestable steel tubes, mont, Colo., the inner tube 120 has an inside diameter of preferably seamless tubes as shown at 120 and 126 in two inches and an outside diameter of 23 inches. The FIG. 2. A hydrogen permeation barrier coating is then outer tube 126 has an inside diameter of three inches formed on the tubes, preferably on the exterior and and an outside diameter of 3 inches. Thus, Aris is inch. 40 interior surfaces of both tubes. The tubes are then as In the example above, At at the top of the heat sembled in nested concentric telescopically spaced rela exchanger is 550 degrees Fahrenheit (700 degrees tion as shown in FIG. 2 and the space between the tubes F.- 150 degrees F). Thus, the temperature gradient is is sealed as by sealing ring 134. The space 132 between substantial and substantial radial heat transfer will oc the tubes is then evacuated and the space is filled with cur in the upper portion of the fluid treatment appara 45 an inert gas, such as neon, argon or xenon. The resultant tus unless the inner pipe 24 is well insulated. insulated tubular is not as subject to insulation degrada The use of an insulated tubular 24 has resulted in a tion because the barrier reduces the permeation of substantial decrease in radial heat losses, however, the atomic hydrogen, as described. insulating qualities have decreased with time. It has Having described the preferred embodiment of the now been discovered that the reduction in the insulating heat exchanger, continuous fluid treatment apparatus

qualities of the insulated tubular is due at least in part to and method of forming an insulated tubular of this in the permeation of atomic hydrogen through the walls of vention, it will be understood that various modifications the insulated tubular into the space 132 between the may be made to the inventions disclosed herein within tubes. Atomic hydrogen is able to permeate the inter the purview of the appended claims. As described, the stices of the metal tubes 120 and 126 into the space 132 between the tubes. The atomic hydrogen then combines 55 heat exchanger and fluid treatment apparatus of this invention may be used in various applications, however, to form hydrogen gas which cannot escape through the the inventions walls. The hydrogen gas then accumulates in the space cal tube or deeparewell particularly adapted for use in verti 132 between the tubes, increasing the thermal conduc used for wet oxidationreaction apparatus such as may be of municipal sludge. The appara tivity of the gas. As described above, the space between tus may, however, be used for treatment of various the walls is filled with an inert gas. The insulated tubu 60 contaminated or waste fluids or contaminated solid lar of this invention therefore includes a hydrogen per meation barrier which reduces the flow of atomic hy waste suspended in a fluid. The apparatus may also be used to treat or convert various materials in a fluid drogen into the space between the tubes.

The most preferred hydrogen permeation barrier reaction requiring elevated temperatures and pressures. comprises a diffusion coating of aluminum on the inner 65 Having described the preferred embodiments of the and outer surfaces of both tubes, 124, 126, 128 and 130. heat exchanger, continuous fluid treatment apparatus The tubes are preferably formed of steel, such that the and method of this invention, I now claim the invention diffusion coating is an iron-aluminum alloy. Aluminum as follows:

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1. A fluid treatment apparatus for continuous treat 5. The continuous fluid treatment apparatus defined ment of fluid wastes at elevated temperatures and pres in claim 3, characterized in that said hydrogen diffusion sures, said fluid treatment apparatus comprising a plu barrier coating comprises an electroplated coating se rality of elongated generally concentric and telescopi lected from the group consisting of nickel and copper. cally nested pipes extending vertically into the ground, 6. A fluid treatment apparatus for continuous chemi said pipes including a first inner pipe having an open cal reaction of fluid wastes with a second reactant at lower end comprising an insulated tubular, said insu elevated temperatures and pressures, said fluid treat lated tubular including generally concentric telescopi ment apparatus comprising a plurality of telescopically cally nested spaced tubes, the space between said tubes nested pipes extending vertically into the ground, said sealed and filled with an inert gas, a second pipe sur 10 pipes including a first inner pipe having an open lower rounding said first pipe in spaced relation having a end comprising an insulated tubular, said insulated tubu closed lower end and communicating with said first lar including generally concentric telescopically nested pipe at its lower end, a third pipe surrounding said sec spaced tubes, the space between said tubes sealed and ond pipe in spaced relation having an opening at its filled with an insulating medium, a second pipe sur lower end and a fourth pipe surrounding said third pipe 15 rounding said first pipe insulated tubular in spaced rela in spaced relation having a closed end and communicat tion having a closed lower end and communicating with ing with said third pipe in spaced relation, hot heat said first pipe at its lower end, a third pipe surrounding transfer fluid received in said first pipe insulated tubular said second pipe in spaced relation having an open end flowing downwardly through said first pipe and recir at its lower end and a fourth pipe surrounding said third culating upwardly between said first pipe and said sec 20 pipe in spaced relation having a closed end and commu ond pipe in heat transfer relation with said fluid waste nicating with said third pipe in spaced relation, hot heat flowing downwardly in the annular space between said transfer fluid received in said first pipe insulated tubular second pipe and said third pipe and said fluid waste flowing downwardly through said first pipe and said recirculating upwardly in the annular space between heat transfer fluid flowing upwardly between said first said third pipe and said fourth pipe to be discharged 25 pipe and said second pipe in heat transfer relation with from said apparatus, the length of said pipes being suffi said fluid waste and said second reactant flowing down cient to create a fluid pressure head sufficient to react wardly in the annular space between said second pipe said fluid waste, and said insulated tubular having a and said third pipe to initiate said chemical reaction hydrogen permeation barrier means limiting permeation between said fluid waste and said second reactant in a of atomic hydrogen into said space between said tubes 30 reaction zone located adjacent the lower extent of said of said insulated tubular, reducing heat losses from said third pipe, said insulated tubular limiting the heat trans heat transfer fluid flowing downwardly in said first pipe fer between said hot heat transfer fluid in said first pipe to the upwardly recirculating heat transfer fluid in an insulated tubular and the upwardly flowing heat trans nular space between said first pipe and said second pipe, fer fluid above said reaction zone, and said fluid waste and defining a predetermined reaction zone in the lower 35 recirculating upwardly in the annular space between portion of said third pipe, whereby said fluid waste is said third pipe and said fourth pipe to be discharged reacted under heat and pressure in said reaction zone. from said apparatus, the length of said pipes being suffi 2. The continuous fluid treatment apparatus defined cient to create a fluid pressure head sufficient to main in claim 1, characterized in that said hydrogen perme tain said reaction of said fluid waste and said second ation barrier means comprises an atomic hydrogen bar 40 reactant at the reaction temperature, and said insulated rier coating on said tubes of said insulated tubular. tubular having means limiting accumulation of hydro 3. The continuous fluid treatment apparatus defined gen in said space between said tubes of said insulated in claim 2, characterized in that said tubes are steel and tubular reducing heat losses from said hot heat transfer said hydrogen barrier coating is selected from the group fluid flowing downwardly in said first pipe to the up consisting of aluminum, nickel and copper. 45 wardly recirculating heat transfer fluid in said annular 4. The continuous fluid treatment apparatus defined space between said first pipe and said second pipe and in claim 3, characterized in that the tubes of said insu maintaining said reaction in said reaction zone in the lated tubular are steel and said hydrogen diffusion bar lower portion of said third pipe, whereby said fluid rier consists of a diffusion coating of aluminum on the waste is reacted under heat and pressure in said reaction inner and outer surfaces of said tubes, forming an iron 50 ZOle. k cit k k k aluminum alloy.