patent · CN115652333A
A low-power resonance electrolysis water method in the production of hydrogen and oxygen
31 January 2023
Translated from Chinese
Machine-translated from Chinese by Google Patents, and offered as a way in rather than as the record. The Chinese is the document — where the two differ, it is the one that counts.
Abstract
The invention provides a low-power-consumption resonance water electrolysis method in oxyhydrogen gas production, which stores resonance natural frequency and phase initial parameters of water molecules or water molecule groups in a CPU controller; the resonance control circuit controls and adjusts the frequency and the phase of the positive and negative electrode plates applied in the electrolytic bath; the resonance control circuit comprises a high-precision excitation signal source and a CPU controller; the dynamic frequency and the phase of the water molecules or the water molecule groups are collected in real time by a measuring unit of a phase-locked loop circuit, and are sent to a high-precision excitation signal source for dynamically adjusting the applied frequency and phase, and after a plurality of cycles, the dynamic frequency and the applied phase are close to or equal to the inherent resonance frequency of the water molecules or the water molecule groups, so that a large number of water molecules or the water molecule groups are simultaneously cracked to generate hydrogen ions and hydroxyl ions. The invention realizes that the power of approximate 1 degree electricity is used for generating hydrogen equivalent to 1 degree electricity and oxygen, thereby greatly reducing the production cost; the sensor and the negative feedback automatically adjust the resonant frequency and the phase in real time, and the low-cost and pollution-free process is realized.
Description
technical field
The invention relates to a low power consumption resonant electrolysis water method in the production of hydrogen and oxygen, belonging to the technical field of electrolytic production of hydrogen and oxygen.
Background technique
There are many methods for preparing hydrogen in the prior art, mainly including and several types:
Fossil fuel hydrogen production: Fossil fuel hydrogen production is a traditional hydrogen production method and an ancient hydrogen production process. However, it relies on fossil fuels and emits greenhouse gases such as carbon dioxide. The fossil fuel commonly used to produce hydrogen is natural gas. my country's natural gas is extremely scarce, the utilization rate of raw materials is low, and the production process is complicated and difficult.
Hydrogen production by methanol reforming: Hydrogen production by methanol steam reforming is a hydrogen production technology developed abroad in the 1980s. It has low investment, quick construction, no emissions and pollution, and high availability of raw materials.
Hydrogen production by industrial by-products: coke oven gas is a hydrogen production process using pressure swing adsorption process. Pure hydrogen is extracted from coke oven gas, a by-product of coking industry. The basic principle is to use solid adsorbent to selectively adsorb gas, and the gas adsorption With the decrease of the partial pressure on the adsorbent, the characteristics of gas mixing and separation and regeneration of the adsorbent are achieved to achieve purification.
Hydrogen production by electrolysis of water: Hydrogen can also be obtained by traditional electrolysis of water. The technology of hydrogen production by electrolysis of water at home and abroad is relatively mature, with high efficiency and simple hydrogen production process. However, due to the high cost of this method, there are few new devices except for the devices that have been built.
The above are several common hydrogen production methods at present. Each method has its own advantages and disadvantages. Either the hydrogen production efficiency is very low, or there is a disadvantage of chemical pollution caused by adding a catalyst, and the noble metal catalyst has the problem of high cost.
In order to solve these problems, the prior art literature discloses the electrolytic hydrogen production by the pulse resonance method, but the hydrogen production efficiency is still very low, and there is still the disadvantage of adding catalysts to cause chemical pollution. Therefore, what the hydrogen production technology pursues is the low-cost and pollution-free process technology expected by industrialization, but there is no report in the prior art.
Contents of the invention
During the research process, the inventor developed a method of using water for resonant electrolysis to realize the generation of hydrogen equivalent to 1 kWh with the power of approximately 1 kWh of electricity in the form of electric field or current resonance, and pure oxygen. The feedback automatic real-time adjustment of resonance frequency and phase technology solves the problems in the existing technology and realizes low-cost and pollution-free technology.
The technical solution provided by the present invention is: a low-power resonant electrolysis water method in the production of hydrogen and oxygen, firstly storing the resonant natural frequency and phase initial parameters of water molecules or water molecular clusters in the CPU controller; then, by The resonance control circuit controls and adjusts the frequency and phase applied to the negative and positive electrode plates in the electrolytic cell; the resonance control circuit includes a high-precision excitation signal source and a CPU controller; when the power is just turned on, the high-precision excitation signal source is controlled by the CPU controller The VCO output of the phase-locked loop circuit in the circuit gives the fundamental frequency and phase excitation signal of the resonant state, which is applied to the water molecule or water molecule group, and then the measurement unit of the phase-locked loop circuit collects the water molecule or water molecule group in real time. The dynamic frequency and phase are sent to the high-precision excitation signal source for dynamic adjustment of the applied frequency and phase. After several cycles, it is close to or equal to the natural resonance frequency of water molecules or water molecular clusters, so that a large number of water molecules or water molecules The molecular clusters collapse simultaneously to produce hydrogen ions and hydroxide ions.
Further, the CPU controller is also connected with a display module and a communication module.
Further, the resonant control circuit also includes a control unit, the cathode and anode electrode plates are arranged in the electrolytic cell at intervals, and a high-precision excitation signal source is connected to the cathode and anode electrode plates, and the control unit is connected to and receives the signal of the high-precision excitation signal source, Load the high-frequency pulse signal on the electrode plate.
Further, the resonance control circuit also includes an A/D unit, the measurement unit of the phase-locked loop circuit is connected to the electric field measurement sensor arranged in the water in the electrolytic tank, and receives the measurement data of the electric field measurement sensor, and the electric field measurement sensor is separated by a certain distance. In the initial state, the excitation frequency and real-time phase are not in the resonance state with the water molecules, and a certain amount of H + and OH - are produced by the weak electrolysis of the water molecules. The current excitation voltage or electric field makes the water molecules The chemical bond tends to break, so that the phase of the electric field signal detected by the electric field measurement sensor increases, and this increase increases the fitting capacitance C detection value formed by the two plates of the electric field measurement sensor, and the C detection is connected in parallel in the measurement The two ends of the varactor diode of the unit increase the total capacity C of the varactor diode, and the phase-locked voltage PD V of the negative terminal of the varactor diode of the measurement unit increases, and the value of PD v is sent to the CPU controller by the A/D unit , compared with the frequency value and real-time phase value of the previous high-precision excitation signal source after being processed by the CPU controller, the difference obtained is used to adjust the excitation signal source, and the frequency of the excitation signal source after the difference compensation is obtained this time value and real-time phase value.
Furthermore, the obtained difference is used to adjust the excitation signal source in two types: increasing the adjustment frequency and real-time phase and decreasing the adjustment frequency and real-time phase; judging by comparing the obtained difference, such as the measured real-time If the phase of water molecules or water molecules increases, then increase the frequency and real-time phase value, otherwise decrease the frequency and real-time phase value.
Further, the two pole plates of the electric field measurement sensor are coated with an insulating layer to eliminate the influence of the current in the water.
Further, the resonance control circuit also includes an electronic switch, the electronic switch is connected to the excitation signal source and the control tube, and the CPU controller controls the opening or closing of the electronic switch, so that the high-frequency sine wave delivered by the excitation signal source is converted through the control tube The high-frequency pulse signal is then sent to the anode electrode plate, and the control tube is a kind of Schottky diode, tunnel diode or IGBT unit.
Further, to make the excitation signal reach the optimal frequency and real-time phase required by water molecules, it is necessary to measure the real-time electric field or conductivity that will reach the resonance state with high precision, and feedback, adjust and control the excitation frequency and phase by the resonance control circuit, Among them, the high-precision measurement uses the measurement method and circuit in the application number 201810109609.0 to measure the real-time electric field or conductivity.
Furthermore, in the electric field measurement, when the electrodes are disturbed by the excitation electric field, the strong electric field generated between the excitation electrodes will have a great influence on the measured electric field signal in the detection electrode. When the excitation water molecules each time will reach In the resonant state, the control briefly turns off the excitation signal source, and then starts the detection of the electric field or conductivity to eliminate the influence of the excitation electric field, and after calculation, it is sent to the excitation unit to readjust the excitation frequency and real-time phase, and N cycles are performed according to the adjustment result , N is a natural number that does not contain 0.
The beneficial technical effects of the present invention are: realize the generation of hydrogen equivalent to 1 degree of electricity with the power of approximately 1 degree of electricity in the form of electric field or current resonance, and can also produce oxygen, greatly reducing the production cost; using sensors plus feedback The automatic real-time adjustment of resonance frequency and phase technology realizes low-cost and pollution-free process.
Description of drawings
The present invention will be further described below in conjunction with the accompanying drawings.
Fig. 1 is the connection structure schematic diagram of the present invention;
FIG. 2 is a schematic structural diagram of a phase-locked loop measurement unit of the present invention.
In the figure: 1. CPU unit, 2. High-precision excitation signal source, 3. Electrolyzer, 4. Electric field measurement sensor, 5. Varactor diode, VCO and phase detector PD of phase-locked loop, 6. A/D unit , 7, gas collector, 8, control unit, 9, electrolysis electrode.
Detailed ways
Example 1
A low-power resonant electrolysis water method in the production of hydrogen and oxygen. First, refer to the relevant resonance parameters of water molecules and obtain the initial parameters of the natural frequency and phase of the resonance on the water molecules or water molecular groups through calculation, and store them in the CPU controller; then The resonance control circuit controls and adjusts the frequency and phase of the negative and positive electrode plates in the electrolytic cell; the resonance control circuit includes a high-precision excitation signal source and a CPU controller; when the power is just turned on, the high-precision excitation is controlled by the CPU controller The VCO output of the phase-locked loop circuit in the signal source gives the fundamental frequency and phase excitation signal of the resonance state, which is applied to the water molecule or water molecule group, and then the measurement unit of the phase-locked loop circuit collects the water molecule or water molecule in real time The dynamic frequency and phase of the group are sent to the high-precision excitation signal source for dynamic adjustment of the applied frequency and phase. After several cycles, it is close to or equal to the natural resonance frequency of the water molecule or the water molecule group, so that a large number of water molecules Or water molecular clusters collapse simultaneously to produce hydrogen ions and hydroxide ions.
The negative and positive electrode plates are arranged at intervals in the electrolytic cell, and a high-precision excitation signal source is connected to the electrode plates of the negative and positive electrodes, and the excitation signal source signal is sent to the control unit, and the high-frequency pulse signal is loaded on the electrode plate; An electric field measurement sensor is installed in the tank, and the electric field measurement sensor is connected to the phase-locked loop measurement circuit, and the phase-locked loop measurement unit of the resonance control circuit measures the dynamic frequency and dynamic phase of the electric field in the electrolytic tank in real time and adjusts the output of the excitation signal source.
The CPU controller is also connected with a display module and a communication module for display and communication.
The resonance control circuit also includes an electronic switch, the electronic switch is connected to the excitation signal source and the control tube, and the CPU controller controls the opening or closing of the electronic switch, so that the high-frequency sine wave transmitted by the excitation signal source is converted into a high-frequency pulse signal by the control tube and then sent to the On the anode electrode plate, the control tube is one of Schottky diode, tunnel diode or IGBT unit.
The electric field measurement sensor is composed of two polar plates separated by a certain distance, and placed in the water in the electrolytic cell. In the initial state, the excitation frequency and real-time phase are not in a resonance state with the water molecules, and a certain amount of H + will be generated due to the weak electrolysis of the water molecules. , OH - , the current excitation voltage or electric field makes the chemical bonds of water molecules develop towards the trend of breaking, so that the phase of the electric field signal detected by the electric field measurement sensor shows a tendency of increasing, that is, accelerating, and this increasing trend will make the two poles of the electric field measuring sensor The detection value of the plate forming fitting capacitance C is increasing, and the signal of this value is sent to both ends of the varactor diode of the phase-locked loop measurement unit, and the C detection is connected in parallel to both ends of the varactor diode to increase the total capacity C of the varactor diode. Cause the phase-locked voltage PD V of the negative terminal of the varactor diode of the phase-locked loop measurement unit to increase, and PD v is sent to the processor unit by the A/D unit 6, and after being processed by the processor unit, it is compared with the frequency value of the last excitation source and Comparing the real-time phase values, the obtained two difference values adjust the excitation signal source in an increasing form, and obtain the frequency and real-time phase of the increased excitation signal source compensated by the difference, and then repeat the above process.
The two difference values obtained may divide the adjustment of the excitation signal source into two steps, increasing the error value to adjust the frequency and real-time phase, and reducing the error value to adjust the frequency and real-time phase; repeating the above process means: combining experience with feedback The correction difference value continues to increase the frequency and real-time phase value to see if the electric field of the real-time water molecule or water molecule group measured by the phase-locked loop counter-measurement unit continues to increase, then continue to increase the frequency of the excitation source and the real-time phase value, otherwise Reduce the frequency of the excitation source and the real-time phase value. After N cycles, it will reach the strongest state and the best resonance state of the electric field generated by electrolysis, so that the water molecules will collapse and crack, and H + and OH - will be generated by the gas of the positive and negative electrodes respectively. The collector collects O2 and H2 .
Example 2
As shown in Figure 1, in the design stage of the electrolytic cell 3, the area and optimal distance of the negative and positive plates are determined according to relevant calculations and empirical values. The natural frequency of water molecules is comprehensively calculated, so as to obtain related parameters such as the excitation frequency and real-time phase to be set. In addition, the electrolysis voltage is calculated and stored according to the distance between the two electrodes.
Connect the high-precision excitation signal source 2 to the two electrolytic electrodes 9, the above-mentioned excitation frequency and real-time phase value are obtained by the CPU unit 1 to control the excitation signal source signal to the control unit 8, and the electronic switch is turned on by the control unit 8, and then sent to Schott The base diode (or tunnel diode or IGBT unit) converts the high-frequency sine wave into a high-frequency pulse signal, and then sends it to the electrolysis electrode 9 of the electrolysis tank 3 to stimulate pure water electrolysis.
The CPU unit 1 is also connected with a display module and a communication module.
Since the current excitation frequency and real-time phase may not be in a resonant state with water molecules, a certain amount of H + and OH - will also be produced due to the weak electrolysis of water molecules, and because the electric field measurement sensor 4 placed in the water in the electrolytic cell is separated by Composed of two polar plates at a certain distance, the generation of the current excitation voltage or electric field makes the chemical bond of the water molecule develop towards the trend of breaking, but it has not really broken, and the phase of the electric field signal detected by the electric field measuring sensor 4 will show an increasing trend. And the trend of this increase will make the two electrode plates of this unit form the fitting capacitance C to increase, and this signal is sent to the two ends of the varactor diode of the phase-locked loop anti-measurement unit 5, that is, C is connected in parallel to the two ends of the varactor diode , so that the total capacity C of the varactor diode increases, see the principle description of the phase-locked loop measurement unit, the C total capacity of the varactor diode in the measurement unit increases, resulting in an increase in the PDV of the measurement unit, and PDv is determined by ⑥A/D After the detection, the value is sent to the CPU unit, and the two difference values obtained after the CPU processing are compared with the frequency value and the real-time phase value of the last excitation source will adjust the excitation signal source to the value that has compensated the above difference in the form of an increase. That is, increase the frequency and real-time phase of the excitation signal source, and then repeat the above process. At this time, there are two steps, one is to increase the error value to adjust the frequency and real-time phase, and the other is to decrease the error value to adjust the frequency and real-time phase, and then to stimulate the electrolysis process, the stronger the electric field intensity measured in these two states shall prevail , and then continue to assume that it is to increase the frequency and real-time phase value with a small empirical value combined with the feedback correction difference. After passing the empirical value N times, the phase of the electric field generated by electrolysis can always reach the strongest state and reach the best. In the resonance state, the water molecules are collapsed and cracked to produce H + , OH - , and the gas collectors at the positive and negative electrodes collect O2 and H2 respectively. To make the water molecules reach the resonant state and split into H + , OH - after a brief stop, the most critical thing is to make the excitation signal reach the optimal frequency and real-time phase required by the current water molecules, which requires the introduction of a detector that is about to reach the resonance The high-precision sensor of the real-time electric field or conductivity of the state, and the control circuit feeds back to adjust and control the excitation frequency and phase. Here, the precision series patent technology that can measure the real-time phase and frequency is more than ten times that of the previous technology is adopted. See the application number 201810109609.0.
The principle description of the phase-locked loop anti-measurement unit: the electric field measurement sensor C detection in Figure 1 is equivalent to the C X fitting capacitance in Figure 2, and Figure 2 provides an ultra-high measurement range, ultra-high stability, and relatively low cost. High-precision displacement measurement method.
Connect the fitting capacitance formed by the sensor measuring displacement or angle variable or hysteresis signal variable in parallel with the varactor diode of the phase-locked loop circuit, and the phase detector cooperates with the LPF to generate the local oscillator frequency value of the VCO oscillation and the setting transmitted by the MCU The frequency value is compared to generate a phase-locked error voltage PD v . The error voltage adjusts the local oscillator frequency in the form of a negative feedback closed loop to make it track and equal to the set frequency of the phase-locked loop PLL, and achieve the same accuracy as the PLL crystal oscillator. Differential integration and The form of the mean value theorem is infinitely approaching or equal to the central value of a phase-locked voltage, and the calibrated real-time error voltage determines the value of the local oscillator frequency, and the error voltage and the variable value of the error voltage are used to reversely measure the phase-locked loop LC oscillator. C The real-time value of the total capacitance, the real-time value of the fitting capacitance and the variable value, the measured value of the displacement or angle or the hysteresis signal is calculated from the fitting capacitance variable value, and the stored temperature, correction capacitance and correction coefficient of the measured value are used for correction , and further obtain ultra-high-precision measurement values, and realize ultra-high-precision measurement of displacement or angle or hysteresis signals.
Ultra-high precision refers to: the accuracy of the measured value is 0.05%, the resolution is 20nm, the measurement range is 300mm, and the repeatability reaches 0.1%.
The error voltage adjusts the local oscillator frequency in the form of a negative feedback closed-loop to make it track and equal to the PLL setting frequency of the phase-locked loop. Or decrease, and adjust the local oscillator frequency up and down until it is equal to the set frequency value. When the frequency is locked, the real-time value of the adjusted voltage is used to reversely calculate the current capacity of the varactor diode; the displacement or angle or pressure sensor generated The variable signal is converted into a capacitance signal to form a fitting capacitance sensor. The fitting capacitance sensor is connected in parallel with the varactor diode, and the varactor diode increases the capacitance of the fitting capacitance. The phase-locked loop reduces the varactor in order to maintain the original frequency value. The current capacitance value of the diode, at this time, the adjusted voltage increases, and the variable of the current capacitance value of the varactor diode is calculated from the increased value of the adjusted voltage, and the current capacitance value of the fitted capacitor is obtained, which is the same as the current capacitance value of the last fitted capacitor pre-stored. Ratio, the variable value of the fitted capacitance is increased or decreased, and the measured value of displacement or angle or pressure is further calculated.
The phase detector cooperates with the LPF to compare the local oscillator frequency value generated by the VCO oscillation with the set frequency value transmitted by the MCU to generate a phase-locked error voltage PD v means: when the two frequency values are different, an error voltage is generated, and the error voltage Feedback to the negative terminal of the varactor diode of the VCO circuit. When the local oscillator frequency value is lower than the set frequency value, the error voltage increases. Since the error voltage is loaded on the negative terminal of the varactor diode, the capacitance of the varactor diode decreases, resulting in The local oscillator frequency signal increases; otherwise, the error voltage decreases, causing the local oscillator frequency to decrease until the phase-locked loop tracks and locks to a set frequency center value, achieving the same or higher precision as the crystal oscillator of the phase-locked loop.
The total value of C of the LC oscillator is correspondingly reduced by the same amount as the fitting capacitance, and at the same time, the adjustment voltage value is correspondingly increased. When the parallel fitting capacitance increases or decreases due to the displacement or angle change, the Adjust the voltage value to increase or decrease accordingly. Calibration by using the stored temperature, correction capacitance and correction coefficient of the measured value refers to storing the correction system of the error caused by the temperature, capacitance and measured value in the MCU, and using these correction systems to correct the measured value, among which the correction capacitance Carry out two measurements with the relative measurement method, and subtract the two voltage values obtained, and the difference obtained is the current capacity value of the correction capacitor, and the correction coefficient is calculated by combining the current correction capacitor capacity with the stored calibration value of the correction capacitor; Use this correction coefficient to correct the real-time variable value of the fitting capacitance, and improve the accuracy, stability and repeatability of the variable value.
The VCO circuit adopts a temperature-compensated crystal oscillator with an accuracy of at least 10 e-16 power, and uses a constant temperature tank VCO circuit with a power accuracy of not less than 0.01%. The variable value of the fitting capacitor is connected to a switch at the positive end of the fitting capacitor and connected to the negative pole of the varactor diode, and the phase-locking error voltage difference PD v difference obtained by turning on and off the switch is the error voltage variable value, and calculate the variable value of the fitted capacitance at the same time. Due to the ultra-high precision, resolution and repeatability of the phase-locked error voltage PD v , the real-time value of the total capacitance of C in the phase-locked loop LC oscillator is measured by using this error voltage and the variable value of the error voltage. The measurement value of the displacement or angle or hysteresis signal can be calculated by using the measured value, and the measurement value can also achieve ultra-high precision, resolution and repeatability, and then use the stored temperature, correction capacitance and correction coefficient of the measurement value for correction to further obtain ultra-high High-precision measurement value, realizing ultra-high-precision measurement of displacement or angle or hysteresis signal. The phase-locked loop voltage is infinitely approaching a "central line" VCO voltage value under the framework of integral differentiation and even Laplace's median value theorem, which is actually a grid voltage, and each grid voltage actually corresponds to The measured value Cx of the displacement, this measured value has actually been C- checked, that is, the real-time frequency value and phase value required by this patented technical solution are obtained, and the frequency value and phase value of the real-time excitation signal source that needs to be modified are calculated at the same time value, thus achieving the purpose of ultra-high precision resonance.
Regarding the solution to the interference of the electric field measurement electrodes by the excitation electric field: the strong electric field generated between the excitation electrodes will have a great impact on the measured electric field signal of the detection electrode, and the signal of the detection electrode is very weak, which is more susceptible to interference. The signal-to-noise ratio of the signal may not be detected, which is not conducive to the detection and processing of the signal in the subsequent stage. Therefore, when the excitation of water molecules mentioned above will reach the resonance state, the excitation signal source can be temporarily turned off, and then the detection of the electric field or conductivity can be started to eliminate the influence of the excitation electric field on it, and the operation will be sent to the excitation The unit readjusts the excitation frequency and real-time phase, and after N cycles, H 2 and O 2 are generated from the two electrodes. Both pole plates of the electric field measurement sensor 4 need to be coated with a very thin insulating layer to eliminate the influence of the current in the water.
The above-mentioned embodiment is an illustration of the technical solution of the present invention, and cannot be used as a limitation to the technical solution of the present invention. Any simple improvement or deformation based on the present invention is within the scope of protection of the present invention.
Claims
1. A low-power resonant electrolysis water method in hydrogen and oxygen production, characterized in that: first the resonant natural frequency and phase initial parameters of water molecules or water molecular clusters are stored in the CPU controller; then, the resonant control circuit Control and adjust the frequency and phase applied to the negative and positive electrode plates in the electrolytic cell; the resonance control circuit includes a high-precision excitation signal source and a CPU controller; when the power is just turned on, the CPU controller controls the lock in the high-precision excitation signal source The VCO output of the phase loop circuit gives the fundamental frequency and phase excitation signal of the resonant state, which is applied to the water molecule or water molecule group, and then the dynamic frequency and Phase, sent to a high-precision excitation signal source for dynamic adjustment of the applied frequency and phase, after several cycles, making it close to or equal to the natural resonance frequency of water molecules or water molecule groups, so that a large number of water molecules or water molecule groups simultaneously The breakdown produces hydrogen ions and hydroxide ions.
2. The low-power resonant electrolysis water method in hydrogen and oxygen production according to claim 1, characterized in that: the resonant control circuit also includes a control unit, the negative and positive electrode plates are arranged in the electrolytic cell at intervals, and The electrode plate is connected with a high-precision excitation signal source, and the control unit is connected with and receives the signal of the high-precision excitation signal source, and loads the high-frequency pulse signal on the electrode plate.
3. The low power consumption resonant electrolysis water method in hydrogen and oxygen production according to claim 1, characterized in that: the CPU controller is also connected with a display module and a communication module.
4. The low-power resonance electrolysis water method in hydrogen and oxygen production according to claim 1, characterized in that: the resonance control circuit also includes an A/D unit, and the measurement unit of the phase-locked loop circuit is connected to the electrolytic cell The electric field measurement sensor in the inner water receives the measurement data of the electric field measurement sensor. The electric field measurement sensor is composed of two plates separated by a certain distance; in the initial state, the excitation frequency and real-time phase are not in the resonance state with the water molecules, and the water The weak electrolysis of molecules produces a certain amount of H + , OH - , the current excitation voltage or electric field makes the chemical bonds of water molecules tend to break, and the phase of the electric field signal detected by the electric field measurement sensor increases. This increase makes the electric field The detection value of the fitting capacitance C formed by the two plates of the measurement sensor increases, and the C detection is connected in parallel at both ends of the varactor diode of the measurement unit, so that the total capacity C of the varactor diode increases, and the measurement value of the varactor diode of the measurement unit increases. The negative terminal phase-locked voltage PD V increases, and the PD v value is sent to the CPU controller by the A/D unit. After being processed by the CPU controller, it is compared with the frequency value and real-time phase value of the previous high-precision excitation signal source, and the obtained difference The value is used to adjust the excitation signal source to obtain the frequency value and real-time phase value of the excitation signal source after the difference compensation.
5. The low-power resonant electrolysis water method in hydrogen and oxygen production according to claim 4, characterized in that: the obtained difference is used to adjust the excitation signal source in two types: increasing the adjustment frequency and real-time phase and decrease to adjust the frequency and real-time phase; judging by the difference obtained by comparison, if the measured real-time phase of water molecules or water molecular clusters shows an increase, then increase the frequency and real-time phase value, otherwise decrease the frequency and real-time phase value.
6. The low-power resonant electrolysis water method in hydrogen and oxygen production according to claim 4, characterized in that: the two pole plates of the electric field measurement sensor are coated with insulating layers to eliminate the influence of current in water on them. Influence.
7. The low-power resonant electrolysis water method in hydrogen and oxygen production according to claim 1, characterized in that: the resonant control circuit also includes an electronic switch, the electronic switch is connected to the excitation signal source and the control tube, and the CPU controller controls When the electronic switch is turned on or off, the high-frequency sine wave sent by the excitation signal source is converted into a high-frequency pulse signal through the control tube and then sent to the anode electrode plate. The control tube is a Schottky diode, a tunnel diode or an IGBT unit. kind.
8. The low-power resonance electrolysis water method in hydrogen and oxygen production according to claim 1, characterized in that: to make the excitation signal reach the optimum frequency and real-time phase required by water molecules, high-precision measurement is required to achieve resonance The real-time electric field or conductivity of the state, and the resonance control circuit feeds back, adjusts and controls the excitation frequency and phase, wherein the high-precision measurement uses the measurement method and circuit in the application number 201810109609.0 to measure the real-time electric field or conductivity.
9. The low-power resonant electrolysis water method in hydrogen and oxygen production according to claim 8, characterized in that: in the electric field measurement, when the electrodes are disturbed by the excitation electric field, due to the strong electric field generated between the excitation electrodes will The electric field signal of the detection electrode has a great influence. When the excitation of water molecules will reach the resonance state each time, the control will temporarily turn off the excitation signal source, and then start the detection of the electric field or conductivity to eliminate the influence of the excitation electric field, and after calculation Send it to the excitation unit to readjust the excitation frequency and real-time phase, and perform N cycles according to the adjustment result, where N is a natural number that does not contain 0.
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- Assignee
- 叶志刚
- Inventors
- 叶志刚; 卢峰; 郭丽; 朱君颜
- Published
- 2023-01-31
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