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established · Water Fuel Cell · computed

Electrode surface finish and area set water's pulsed-breakdown ceiling

Wetz et al. (2 mm gap, >1 MV/cm, >5 kA): the pulsed holdoff field of a water dielectric RISES as electrode surface roughness falls and as effective conducting area falls. Microprotrusions produce localized field enhancements many times the mean field — each is a preferential breakdown site — so a smoother plate holds off more volts. Holdoff scales inversely with area: a larger plate exposes more microprotrusions, lowering the sustainable field. Two breakdown paths: (1) charge injection at the electrode/water interface, (2) electron-impact ionization in low-density (bubble) regions. Corollary for the WFC/gas-processor: polish the plates and keep effective area no larger than needed to raise the sub-breakdown ceiling. Roughness and area are levers on the leakage/Figure-8 picture, not just geometry.

Basis

Confidence
0.85
Published
19 Aug 2026
Origin
StanBot lab notebook
Component
wfc
Source Ref
Wetz, Mankowski & Kristiansen (Texas Tech) — Electrode Area & Surface Roughness on Pulsed Breakdown of Water [page 4296]
Recorded At
2026-08-16 23:36:19.946102

breakdown water-dielectric electrode figure-8 reference